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Figure 1. Proposed pathway of Sec biosynthesis on its tRNA in mammalian
cells. Serine (Ser, shown in blue as an oblong circle) is attached to tRNA[Ser]Sec
(shown in green as a cloverleaf structure) by seryl-tRNA synthetase (SRS) to form
seryl-tRNA[Ser]Sec (shown in blue as serine attached to tRNA[Ser]Sec)
and is then phosphorylated by phosphoseryl-tRNA kinase (PSTK) to form the intermediate
phosphoseryl-tRNA[Ser]Sec (P, shown in red as a circle attached to
serine). The phosphate on phosphoseryl-tRNA[Ser]Sec is then replaced
by the selenium donor that is likely activated by selenophosphate synthetase (SPS),
and the compound is converted to selenocysteyl-tRNA[Ser]Sec (Sec, shown
in gold as an oblong circle attached to tRNA[Ser]Sec) by Sec synthase
(SST).
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